CHEMY203-19A (HAM)

Inorganic Chemistry

15 Points

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Division of Health Engineering Computing & Science
School of Science

Staff

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Convenor(s)

Bill Henderson

Bill Henderson
4656
E.3.21
Students are welcome to come to my office or make an appointment via e-mail
bill.henderson@waikato.ac.nz

Lecturer(s)

Graham Saunders

Graham Saunders
4092
CD.3.01
Please e-mail me to make an appointment
graham.saunders@waikato.ac.nz

Administrator(s)

Placement Coordinator(s)

Tutor(s)

Student Representative(s)

Lab Technician(s)

Librarian(s)

: cheryl.ward@waikato.ac.nz

You can contact staff by:

  • Calling +64 7 838 4466 select option 1, then enter the extension.
  • Extensions starting with 4, 5, 9 or 3 can also be direct dialled:
    • For extensions starting with 4: dial +64 7 838 extension.
    • For extensions starting with 5: dial +64 7 858 extension.
    • For extensions starting with 9: dial +64 7 837 extension.
    • For extensions starting with 3: dial +64 7 2620 + the last 3 digits of the extension e.g. 3123 = +64 7 262 0123.
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Paper Description

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This paper covers aspects of inorganic chemistry including structure and reactivity of the main-group elements; point-group symmetry; molecular orbital and crystal field theories; transition metal coordination complexes.

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Paper Structure

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This paper is taught through:

- 24 lectures

- one three hour laboratory session every second week plus laboratory reports

- an essay on an individual assigned topic in inorganic chemistry.

- an assignment relating to Graham Saunders' lectures.

A one-hour tutorial will be held each week, to discuss various aspects of the course, including revision of lecture content, essay preparations, and interpretation of laboratory results etc.

Important note for international students: For international students in New Zealand under student visas, regular attendance is part of your visa obligation and is checked as a requirement on the University under the Code of Practice for the Pastoral Care of International Students, to which the University is a signatory. Academic staff are formally required to monitor attendance in classes and submission of compulsory assessment events/items and to report to Waikato International in the event that any problem with irregular attendance or non-submission is not resolved.


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Learning Outcomes

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Students who successfully complete the course should be able to:

  • (as follows)
    1. Rationalise important trends in structure, bonding and reactivity in main group elements and their compounds of groups 1-2 and 13-18.
    2. Use valence shell electron pair repulsion (VSEPR) theory to predict the geometries of polyatomic compounds.
    3. Identify symmetry elements in simple polyatomic compounds and assign a point group.
    4. Apply a qualitative description of molecular orbital (MO) theory to simple diatomic and polyatomic compounds (organic and inorganic) and to use MO methods in rationalisation of molecular properties such as magnetism and bonding characteristics.
    5. Apply an understanding of electron configurations, and crystal field theory to account for the properties of transition metal coordination complexes (excluding organometallic compounds) and to interpret structural, spectroscopic and magnetic data for transition metal compounds.
    6. Apply the rules of nomenclature to name transition metal coordination complexes.
    7. Identify different types of isomerism commonly found in coordination complexes.
    8. Carry out syntheses of transition metal coordination complexes and/or main group compounds under direction, and characterise the products as appropriate by magnetic susceptibility measurements, UV-visible spectroscopy, IR spectroscopy, mass spectrometry or NMR spectroscopy.
    9. Search for structures using the Cambridge Structural Database.
    10. Carry out qualitative investigations into the chemistry of transition metal compounds and to account for experimental observations.
    11. Write concise and clear reports with coherent discussion supported by appropriate referencing and using appropriate language and formatting.
    Linked to the following assessments:
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Assessment

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This paper is 50% internally assessed, and there is a final examination worth 50%.

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Assessment Components

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The internal assessment/exam ratio (as stated in the University Calendar) is 50:50. There is no final exam. The final exam makes up 50% of the overall mark.

The internal assessment/exam ratio (as stated in the University Calendar) is 50:50 or 0:0, whichever is more favourable for the student. The final exam makes up either 50% or 0% of the overall mark.

Component DescriptionDue Date TimePercentage of overall markSubmission MethodCompulsory
1. Test 1
5 Apr 2019
12:00 PM
5
  • In Class: In Lecture
2. Essay
10
  • Online: Submit through Moodle
  • Hand-in: Faculty Information (FG Link)
3. Assignment
20 May 2019
5:00 PM
5
  • Hand-in: Faculty Information (FG Link)
4. Laboratory performance
6
  • Other:
5. Laboratory reports
24
  • Hand-in: Faculty Information (FG Link)
6. Exam
50
  • Other:
✔
Assessment Total:     100    
Failing to complete a compulsory assessment component of a paper will result in an IC grade
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Required and Recommended Readings

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Required Readings

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A number of textbooks relevant to CHEMY203 can be obtained, in e-book format, for no charge, through Waikato Reading Lists.

For students continuing to inorganic chemistry at Level 3, Inorganic Chemistry, by C. E. Housecroft and A. G. Sharpe (Pearson), available in the Library at QD151.3 .H68 2012 is a very useful resource. The Library also contains a number of other general inorganic and coordination chemistry textbooks that will be of use.

For students proposing to advance inorganic chemistry to MSc level, the following is recommended a: N.N. Greenwood and A. Earnshaw, Chemistry of the Elements (Pergamon), or F.A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry (Wiley-Interscience).

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Recommended Readings

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Practical Skills in Chemistry, second Edition, J. R. Dean et al, Prentice Hall, 2001 is a very useful resource; several copies are available in the Library. This book contains material on general skills (study and examination skills, IT and library resources, communicating information and presenting data), together with information directly relevant to the paper (writing essays, reporting practical work, writing literature reviews. It also contains information on essential practical skills in chemistry (recrystallisation, reflux, evaporation, infrared spectroscopy, NMR spectroscopy, mass spectrometry). QD33.2 .P73 2011

d-Block Chemistry

Chemical Bonding

Both these very readable titles are by M.J. Winter, and published by Oxford University Press. A limited number of copies are available in the library and bookstore

A variety of Library resources are available for the assignment, and include a variety of reference works such as Encyclopedias and multi-volume reference works. Details of these will be provided on the Moodle page.

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Other Resources

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Lecture notes can be downloaded and printed from the Moodle page. The laboratory manual can likewise be self-printed, or a bound copy purchased from Waikato Print.

Lectures will be recorded using Panopto, though we are unable to guarantee the quality or even existence of recordings in the unlikely event that serious technical issues arise.

A molecular model kit will be a valuable tool for the three-dimensional visualisation of molecules. These can be bought from internet trading companies, or alternatively the Chemistry Programme has a limited number for sale. To view and/or purchase one of these please contact Bill Henderson in the first instance.

All students taking CHEMY203 must have a laboratory coat, which will be required for all laboratory classes. This can be purchased from the Science Store if you do not already have one.
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Online Support

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This paper has a Moodle page (http://elearn.waikato.ac.nz) where you will be able to access lecture notes, the laboratory manual, and other useful resources.

PLEASE NOTE: Moodle will be used for class notices etc. and it is your responsibility to check the site regularly. Instructions provided on Moodle and in laboratory classes are considered to be given to the class as a whole.

A number of online quizzes will be available on Moodle, and students are strongly recommended to complete these as an aid to understanding the lecture content.

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Workload

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The total workload expected for this paper is 150 hours.

There are a total of 24 hours of lectures, plus up to an additional 12 hours of tutorials. Students are required to complete 18 hours of laboratory work.

The remaining hours are to be managed by the student to complete the weekly laboratory reports, complete various learning activities, work on the essay and assignment, and to study for the test and final exam.


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Linkages to Other Papers

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This paper is required for the Chemistry major.
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Prerequisite(s)

Prerequisites: CHEMY101 or CHEM111

Corequisite(s)

Equivalent(s)

Restriction(s)

Restricted papers: CHEM203, CHEM211, CHEM213

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